Identification by stopped-exchange solution /sup 31/P NMR spectroscopy of the stepwise formation of (AgL/sub n/)PF/sub 6/ (n = 1-4). Comparison of metal-phosphorus coupling constants for triphenylphosphine and 5-phenyldibenzophosphole
Journal Article
·
· Inorg. Chem.; (United States)
The coordination properties of 5-phenyldibenzophosphate (PhDBP) have been studied extensively. The stepwise formation of (L/sub n/Ag)/sup +/PF/sub 6//sup -/ (n = 1-4) for L = PhDBP and PhP/sub 3/ observed in situ by stopped-exchange solution /sup 31/P NMR spectroscopy is reported herein. The relative coordinating properties of PhDBP and PhP/sub 3/ are compared. 21 references, 1 figure, 2 tables.
- Research Organization:
- Univ. of Guelph, Ontario
- OSTI ID:
- 5477614
- Journal Information:
- Inorg. Chem.; (United States), Vol. 26:25
- Country of Publication:
- United States
- Language:
- English
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X-ray crystal structure and homonuclear sup 31 P- sup 31 P. delta. /J-resolved NMR spectroscopic studies of (AgIr sub 2 (dimen) sub 4 (PPh sub 3 ) sub 2 )(PF sub 6 ) sub 3. Observation of a statistical mixture of head/tail isomers
Variable temperature /sup 31/P and /sup 19/F NMR studies of Fe(CO)/sub 3/(PF/sub 3/)/sub 2/ and Fe(CO)/sub 2/(PF/sub 3/)/sub 3/
Phosphole complexes of Gold(I) halides: Comparison of solution and solid-state structures by a combination of solution and CP/MAS sup 31 P NMR spectroscopy and x-ray crystallography
Journal Article
·
Wed Oct 31 00:00:00 EST 1990
· Inorganic Chemistry; (USA)
·
OSTI ID:5477614
Variable temperature /sup 31/P and /sup 19/F NMR studies of Fe(CO)/sub 3/(PF/sub 3/)/sub 2/ and Fe(CO)/sub 2/(PF/sub 3/)/sub 3/
Journal Article
·
Wed Jun 01 00:00:00 EDT 1977
· J. Chem. Phys.; (United States)
·
OSTI ID:5477614
Phosphole complexes of Gold(I) halides: Comparison of solution and solid-state structures by a combination of solution and CP/MAS sup 31 P NMR spectroscopy and x-ray crystallography
Journal Article
·
Wed Feb 07 00:00:00 EST 1990
· Inorganic Chemistry; (USA)
·
OSTI ID:5477614
+2 more
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AROMATICS
MOLECULAR STRUCTURE
ORGANIC PHOSPHORUS COMPOUNDS
SILVER COMPLEXES
CHEMICAL SHIFT
EXPERIMENTAL DATA
NMR SPECTRA
PHOSPHORUS 31
COMPLEXES
DATA
INFORMATION
ISOTOPES
LIGHT NUCLEI
NUCLEI
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
PHOSPHORUS ISOTOPES
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
400202 - Isotope Effects
Isotope Exchange
& Isotope Separation
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AROMATICS
MOLECULAR STRUCTURE
ORGANIC PHOSPHORUS COMPOUNDS
SILVER COMPLEXES
CHEMICAL SHIFT
EXPERIMENTAL DATA
NMR SPECTRA
PHOSPHORUS 31
COMPLEXES
DATA
INFORMATION
ISOTOPES
LIGHT NUCLEI
NUCLEI
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
PHOSPHORUS ISOTOPES
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
400202 - Isotope Effects
Isotope Exchange
& Isotope Separation