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Uranium and thorium decay series disequilibria in young volcanic rocks

Thesis/Dissertation ·
OSTI ID:5470609

Two of the central questions in igneous geochemistry that study of radioactive disequilibria can help to answer are: what are the rates of magma genesis; and what are the timescales of magma separation and transport. In addition to the temporal information that may be extracted from disequilibria data, the {sup 230}Th/{sup 232}Th of a young rock may be used as a tracer of the Th/U ratio of its source region. Measurements were made by isotope dilution alpha-spectrometry of {sup 238}U, {sup 234}U, {sup 230}Th, and {sup 232}Th in 20 subduction related, 3 oceanic intraplate, and 10 continental intraplate volcanics. {sup 210}Pb was measured in all, {sup 226}Ra was measured in about half, and {sup 228}Th was measured in 10 of the most recent samples. Disequilibrium between {sup 228}Th and {sup 232}Th was found only in the Nacarbonatite samples from Oldoinyo Lengai volcano in Tanzania, which is attributable to {sup 228}Ra/{sup 232}Th {approximately} 27 at the time of eruption. These rocks also have {sup 226}Ra/{sup 230}Th > 60. Three Ra-enrichment models are developed which constrain carbonatite magma formation at less than 20 years before eruption. The effects of different partial melting processes on the {sup 238}U decay series are investigated. If mid-ocean ridge basalts are formed by a dynamic melting process, the {sup 230}Th/{sup 232}Th of the basalts provides a minimum estimate of the Th/U ratio of the source region. The {sup 238}U enrichment in arc volcanics is probably the results of metasomatism of the source by fluids derived from the subducting slab, and the {sup 230}Th enrichment observed for other volcanics is probably due to the partial melting process in the absence of U-bearing fluids.

Research Organization:
California Univ., Santa Cruz, CA (USA)
OSTI ID:
5470609
Country of Publication:
United States
Language:
English

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