Paths for the unimolecular decomposition of methanol following multitphoton infrared excitation
Journal Article
·
· High Energy Chem. (Engl. Transl.); (United States)
OSTI ID:5469503
This paper presents a laser induced fluorescence method used to study the formation of OH and CH radicals after multiphoton IR excitation of CH/sub 3/OH. A methanol dissociation mechanism is presented which is in qualitative agreement with the experimental results. It is shown that by varying the excitation conditions it is possible to control the ratio of the rates of unimolecular decomposition along different paths.
- Research Organization:
- M.V. Lomonosov Moscow State Univ.
- OSTI ID:
- 5469503
- Journal Information:
- High Energy Chem. (Engl. Transl.); (United States), Journal Name: High Energy Chem. (Engl. Transl.); (United States) Vol. 19:6; ISSN HIECA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
ALCOHOLS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CONTROL
DECOMPOSITION
DISSOCIATION
DISSOCIATION ENERGY
ELECTROMAGNETIC RADIATION
ENERGY
ENERGY DENSITY
FLUORESCENCE
HYDROXY COMPOUNDS
INFRARED RADIATION
KINETICS
LASER RADIATION
LUMINESCENCE
METHANOL
MULTI-PHOTON PROCESSES
ORGANIC COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
PRESSURE DEPENDENCE
PROCESS CONTROL
RADIATIONS
RADICALS
REACTION KINETICS
RESONANCE FLUORESCENCE
YIELDS
400500* -- Photochemistry
ALCOHOLS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CONTROL
DECOMPOSITION
DISSOCIATION
DISSOCIATION ENERGY
ELECTROMAGNETIC RADIATION
ENERGY
ENERGY DENSITY
FLUORESCENCE
HYDROXY COMPOUNDS
INFRARED RADIATION
KINETICS
LASER RADIATION
LUMINESCENCE
METHANOL
MULTI-PHOTON PROCESSES
ORGANIC COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
PRESSURE DEPENDENCE
PROCESS CONTROL
RADIATIONS
RADICALS
REACTION KINETICS
RESONANCE FLUORESCENCE
YIELDS