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Title: Diffusion-controlled decohesion using a Cu-Sn alloy as a model system

Conference ·
OSTI ID:5465930

This research deals with a mode of brittle intergranular fracture in which a surface adsorbed embrittling element is driven into a grain boundary as a result of the application of a tensile stress across the boundary. A Cu-8%Sn alloy has been employed to explore this phenomenon, since tin is a surface-active element, and this alloy is known to suffer intergranular weakness at elevated temperatures. Intergranular cracking occurred by brittle, discontinuous crack advance at 265{degrees}C in vacuum with an average rate of 0.1{mu}m/sec. This behavior is analogous to sulfur-induced stress-relief cracking in steels and several cases of liquid-metal embrittlement, suggesting that this phenomenon has a generic nature.

Research Organization:
Pennsylvania Univ., Philadelphia, PA (United States). Dept. of Materials Science and Engineering
Sponsoring Organization:
USDOE; National Science Foundation (NSF); USDOE, Washington, DC (United States); National Science Foundation, Washington, DC (United States)
DOE Contract Number:
FG02-87ER45290
OSTI ID:
5465930
Report Number(s):
CONF-911202-71; ON: DE92011645
Resource Relation:
Conference: Annual fall meeting of the Materials Research Society, Boston, MA (United States), 2-6 Dec 1991
Country of Publication:
United States
Language:
English