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Title: Process for removing hydrogen sulfide from gases particularly coal pyrolysis gases

Patent ·
OSTI ID:5465897

Hydrogen sulfide is first removed by ammoniacal liquor from coke oven gas in the bottom part of a gas scrubber. In the top part of the scrubber, two consecutively-arranged fine scrubbing stages remove hydrogen sulfide by treating the gases, in the upper stage, with a caustic soda solution or a caustic potash solution. Beneath the upper scrubbing stage is the second fine scrubbing stage fed with a subflow of an aqueous carbonate solution collecting at the outlet of the upper fine scrubbing stage and a subflow of cooled, regenerated carbonate solution discharged from the hydrogen-sulfide/hydrogen-cyanide stripper. From the hydrogen-sulfide/hydrogen-cyanide stripper, a second subflow is admixed with coal liquor for removing fixed ammonia therefrom in a separator. The separator produces water vapor with carbon dioxide vapors that are delivered to the hydrogen-sulfide/hydrogen-cyanide stripper for regenerating the aqueous carbonate washing solution.

Assignee:
Dr.C. otto and Comp. GmbH (Germany, Federal Republic of)
Patent Number(s):
US 4499060
OSTI ID:
5465897
Resource Relation:
Patent Priority Date: Priority date 4 Feb 1983, Germany, Federal Republic of (F.R. Germany); Other Information: PAT-APPL-463678
Country of Publication:
United States
Language:
English