Development of unique catalysts for hydrodenitrogenation of coal-derived liquids. First quarterly report, September 15-December 15, 1978
Four experimental runs were made; two used decahydroquinoline as reactant and two runs were made using orthoethylaniline and quinoline-N-oxide respectively. The decahydroquinoline runs indicate that the carbon-nitrogen bond scission is not thermal but clearly catalytic. Important findings resulted from the run using o-ethylaniline and future runs will help define reaction pathways. Quinoline-N-oxide was rapidly deoxygenated to form quinoline under the conditions tested. Future runs will be conducted in the absence of hydrogen to avoid deoxidation of quinoline-N-oxide and to find out whether carbon-nitrogen bond scission can be promoted by the addition of oxygen to the quinoline molecule. A review paper has been prepared that reviews the existing chemistry and technology for hydrodenitrogenation and projects catalyst and process needs for hydrodenitrogenation of synthetic feedstocks and heavy petroleum liquids. It projects what should be a more effective means and more rational basis for the design and development of more active and more selective catalysts for hydrodenitrogenation and attempts some speculations on potentially fruitful direction to be followed in both catalyst and process development.
- Research Organization:
- Delaware Univ., Newark (USA). Dept. of Chemical Engineering
- DOE Contract Number:
- EI-78-S-01-3297
- OSTI ID:
- 5454757
- Report Number(s):
- FE-3297-1
- Country of Publication:
- United States
- Language:
- English
Similar Records
Development of unique catalysts for hydrodenitrogenation of coal-derived liquids. Third quarterly report, March 15-June 15, 1979
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Related Subjects
COAL LIQUIDS
DENITRIFICATION
HYDROGENATION
CATALYSTS
CHEMICAL BONDS
CLEAVAGE
COAL LIQUEFACTION
EXPERIMENTAL DATA
GRAPHS
PETROLEUM
REFINING
RESEARCH PROGRAMS
TABLES
VISCOSITY
CHEMICAL REACTIONS
CRYSTAL STRUCTURE
DATA
DATA FORMS
ENERGY SOURCES
FOSSIL FUELS
FUELS
INFORMATION
LIQUEFACTION
MICROSTRUCTURE
NUMERICAL DATA
PROCESSING
THERMOCHEMICAL PROCESSES
010402* - Coal
Lignite
& Peat- Purification & Upgrading
010405 - Coal
Lignite
& Peat- Hydrogenation & Liquefaction