Cathode preparation method for molten carbonate fuel cell
Patent
·
OSTI ID:5453951
A method of preparing a cathode structure for use in a fuel cell with a molten carbonate salt electrolyte is described comprising: providing a porous sintered plaque of nickel metal that is substantially free of lithium; oxidizing the nickel metal in the porous plaque substantially free of lithium to form nickel oxide by contact with an oxygen containing gas at a temperature of no more than about 600/sup 0/C to 700/sup 0/C; and subsequently adding to the plaque a limited amount of lithium salt at a temperature of no more than 600/sup 0/-700/sup 0/C to lithiate the nickel oxide tgo a lithium level of about 1-6 atom percent lithium while maintaining the structure integrity of the plaque.
- Assignee:
- Dept. of Energy, Washington, DC
- Patent Number(s):
- US 4721513
- OSTI ID:
- 5453951
- Resource Relation:
- Patent File Date: Filed date 28 Jan 1982
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
30 DIRECT ENERGY CONVERSION
36 MATERIALS SCIENCE
MOLTEN CARBONATE FUEL CELLS
CATHODES
NICKEL ALLOYS
FABRICATION
HIGH TEMPERATURE
NICKEL OXIDES
OXIDATION
SINTERING
ALLOYS
CHALCOGENIDES
CHEMICAL REACTIONS
DIRECT ENERGY CONVERTERS
ELECTROCHEMICAL CELLS
ELECTRODES
FUEL CELLS
HIGH-TEMPERATURE FUEL CELLS
NICKEL COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
300503* - Fuel Cells- Materials
Components
& Auxiliaries
360101 - Metals & Alloys- Preparation & Fabrication
36 MATERIALS SCIENCE
MOLTEN CARBONATE FUEL CELLS
CATHODES
NICKEL ALLOYS
FABRICATION
HIGH TEMPERATURE
NICKEL OXIDES
OXIDATION
SINTERING
ALLOYS
CHALCOGENIDES
CHEMICAL REACTIONS
DIRECT ENERGY CONVERTERS
ELECTROCHEMICAL CELLS
ELECTRODES
FUEL CELLS
HIGH-TEMPERATURE FUEL CELLS
NICKEL COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
300503* - Fuel Cells- Materials
Components
& Auxiliaries
360101 - Metals & Alloys- Preparation & Fabrication