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U.S. Department of Energy
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SRP moderator impurities and purification deionizers (RTA-631-R)

Technical Report ·
OSTI ID:5452811
There are more anionic than cationic impurities in the moderator, due to nitric acid and CO/sub 2/. The principal impurities removed by the anion resin are NO/sub 3//sup -/, dissolved CO/sub 2/, and SO/sub 4//sup - -/. From an exhausted mixed-bed deionizer, H/sub 2/CO/sub 3/ is the first component eluted. Nitrate acts as the elutriant, but it does not displace SO/sub 4//sup - -/. No evidence for gross release of Cl/sup -/ was found in minipure resin columns run past initial depletion. I/sup 131/ is released after elution of H/sub 2/CO/sub 3/ has proceeded for a time. The cationic impurities include Al, Fe, Ca, Mg, Mn, Cr, and Co, and the radionuclides Na/sup 24/, Np/sup 239/, and Mn/sup 56/. In addition to the ionic impurities, particulate matter, consisting mainly of iron and aluminum oxides, is filtered out by the resin to the extent of about 1 wt % of the moist resin. Pressure surges will result in release of this material from the loaded column back into the effluent stream.
Research Organization:
Du Pont de Nemours (E.I.) and Co., Aiken, SC (USA). Savannah River Lab.
DOE Contract Number:
AC09-76SR00001
OSTI ID:
5452811
Report Number(s):
DPST-62-191; ON: DE84005583
Country of Publication:
United States
Language:
English