Correlation between Core-Hole Polarization and Localized Bond Rupture Probed by Anisotropy in the Photofragmentation of F 1s Excited SF{sub 6}
Journal Article
·
· Physical Review Letters
- Research Institute for Scientific Measurements, Tohoku University, Sendai 980-77 (Japan)
- Institute of Applied Physics, University of Tsukuba, Tsukuba 305 (Japan)
- Institute for Chemical Research, Kyoto University, Uji, Kyoto 611 (Japan)
Anisotropic photofragmentation of SF{sub 6} following F 1s excitation is ascribed to the localization of the valence holes created as a result of the Auger decay of the F 1s core hole, itself polarized by excitation with linearly polarized light. Theoretical calculations based on the localized core-hole model are in reasonable agreement with the observation. {copyright} {ital 1997} {ital The American Physical Society}
- OSTI ID:
- 544977
- Journal Information:
- Physical Review Letters, Vol. 79, Issue 18; Other Information: PBD: Nov 1997
- Country of Publication:
- United States
- Language:
- English
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