Process for the production of Boronaaronate molecular sieve using ethylenediamine and quinoline or isoquinoline

Patent · Tue Jan 26 04:00:00 EST 1988

OSTI ID:5442272

Haddad, M S; Schimandle, J J

This patent describes a method for preparing a crystalline molecular sieve composition having in terms of mole ratios of oxides: 0.9 +- 0.2M/sub 2/n/O:B/sub 2/O/sub 3/:ySiO/sub 2/:zH/sub 2/O wherein M is a cation of valence n, y is between 2 and about 700, and z is between 0 and about 200 and having the X-ray diffraction pattern substantially as shown in Table I which method comprises reacting under crystallization conditions an aqueous mixture containing an oxide of boron, ethylenediamine, an oxide of silicon, and an organic material selected from the group consisting of quinoline and isoquinoline in the substantial absence of alkali or alkaline earth metal ions wherein the mole ratio of the material to silica is between about 0.2 and about 3.0 the mole ratio of silica to oxide of boron is between about 5 and about 150, and the mole ratio of water to silica is between 15 and about 80.

• Assignee: Amoco Corp., Chicago, IL
• Patent Number(s): US 4721607
• OSTI ID: 5442272
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ADSORBENTS
ALKENES
AMINES
AQUEOUS SOLUTIONS
AROMATICS
AZAARENES
AZINES
BORON COMPOUNDS
BORON OXIDES
CATIONS
CHALCOGENIDES
CHARGED PARTICLES
CHEMICAL COMPOSITION
CHEMICAL PREPARATION
COHERENT SCATTERING
CRYSTALLIZATION
DIFFRACTION
DISPERSIONS
ETHYLENE
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
IONS
MIXTURES
MOLECULAR SIEVES
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHASE TRANSFORMATIONS
PYRIDINES
QUINOLINES
SCATTERING
SILICON COMPOUNDS
SILICON OXIDES
SOLUTIONS
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
VALENCE
X-RAY DIFFRACTION