The effect of chemical additives on the synthesis of ethanol
The objective of this research was to investigate the reaction mechanism of higher alcohol and aldehyde synthesis from syngas and the role of additives in the synthesis. An in situ IR reaction system and probe molecule technique were developed to study adsorbed species, active sites, and reaction pathway during reaction. The catalysts used for this study included silica-supported Rh, Ru, and Ni. (VC)
- Research Organization:
- Akron Univ., OH (United States). Dept. of Chemical Engineering
- Sponsoring Organization:
- USDOE; USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG22-87PC79923
- OSTI ID:
- 5440087
- Report Number(s):
- DOE/PC/79923-T11; ON: DE92013242
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
01 COAL, LIGNITE, AND PEAT
ETHANOL
SYNTHESIS
NICKEL
CATALYTIC EFFECTS
RHODIUM
RUTHENIUM
SILICON OXIDES
SYNTHESIS GAS
CONVERSION
ADDITIVES
CHEMICAL REACTION KINETICS
INFRARED SPECTROMETERS
PROGRESS REPORT
ALCOHOLS
CHALCOGENIDES
DOCUMENT TYPES
ELEMENTS
FLUIDS
GASES
HYDROXY COMPOUNDS
KINETICS
MEASURING INSTRUMENTS
METALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PLATINUM METALS
REACTION KINETICS
SILICON COMPOUNDS
SPECTROMETERS
TRANSITION ELEMENTS
010408* - Coal
Lignite
& Peat- C1 Processes- (1987-)
ETHANOL
SYNTHESIS
NICKEL
CATALYTIC EFFECTS
RHODIUM
RUTHENIUM
SILICON OXIDES
SYNTHESIS GAS
CONVERSION
ADDITIVES
CHEMICAL REACTION KINETICS
INFRARED SPECTROMETERS
PROGRESS REPORT
ALCOHOLS
CHALCOGENIDES
DOCUMENT TYPES
ELEMENTS
FLUIDS
GASES
HYDROXY COMPOUNDS
KINETICS
MEASURING INSTRUMENTS
METALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PLATINUM METALS
REACTION KINETICS
SILICON COMPOUNDS
SPECTROMETERS
TRANSITION ELEMENTS
010408* - Coal
Lignite
& Peat- C1 Processes- (1987-)