Preconversion catalytic deoxygenation of phenolic functional groups
Technical Report
·
OSTI ID:5429762
The deoxygenation of phenols by carbon monoxide mediated by Ir(triphos)(OAr) has provided us with a catalytic phenol deoxygenation pathway, through the elimination of CO{sub 2} and formation of a benzyne intermediate. Although the (Pt(triphos)(O-Ph- Me))PF{sub 6} system is not expected to be as efficient a catalyst as come of the other transition metals systems we are currently exploring, it will provide more information about the deoxygenation mechanism in these triphos complexes. This is due to the presence of the structurally sensitive {sup 31}P-{sup 195}Pt coupling constant and comparisons to the extensively studied Pt(dppe)(O-Ph){sub 2} systems.
- Research Organization:
- Purdue Univ., Lafayette, IN (United States). Dept. of Chemistry
- Sponsoring Organization:
- USDOE; USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG22-89PC89770
- OSTI ID:
- 5429762
- Report Number(s):
- DOE/PC/89770-T5; ON: DE92013922
- Country of Publication:
- United States
- Language:
- English
Similar Records
Preconversion catalytic deoxygenation of phenolic functional groups. Quarterly technical progress report, September 30, 1991--December 31, 1991
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·
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·
OSTI ID:5429762
Preconversion catalytic deoxygenation of phenolic functional groups. Quarterly technical progress report, April 1, 1992--June 30, 1992
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Technical Report
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·
OSTI ID:5429762
Related Subjects
01 COAL, LIGNITE, AND PEAT
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
IRIDIUM
CATALYTIC EFFECTS
OXYGEN
REMOVAL
PLATINUM
ARGON
CARBON MONOXIDE
CHEMICAL BONDS
CHEMICAL REACTION KINETICS
HYDROGENATION
PHENOLS
PHOSPHORUS
PROGRESS REPORT
THERMODYNAMICS
AROMATICS
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
DOCUMENT TYPES
ELEMENTS
FLUIDS
GASES
HYDROXY COMPOUNDS
KINETICS
METALS
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PLATINUM METALS
RARE GASES
REACTION KINETICS
TRANSITION ELEMENTS
010402* - Coal
Lignite
& Peat- Purification & Upgrading
010405 - Coal
Lignite
& Peat- Hydrogenation & Liquefaction
400201 - Chemical & Physicochemical Properties
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
IRIDIUM
CATALYTIC EFFECTS
OXYGEN
REMOVAL
PLATINUM
ARGON
CARBON MONOXIDE
CHEMICAL BONDS
CHEMICAL REACTION KINETICS
HYDROGENATION
PHENOLS
PHOSPHORUS
PROGRESS REPORT
THERMODYNAMICS
AROMATICS
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
DOCUMENT TYPES
ELEMENTS
FLUIDS
GASES
HYDROXY COMPOUNDS
KINETICS
METALS
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PLATINUM METALS
RARE GASES
REACTION KINETICS
TRANSITION ELEMENTS
010402* - Coal
Lignite
& Peat- Purification & Upgrading
010405 - Coal
Lignite
& Peat- Hydrogenation & Liquefaction
400201 - Chemical & Physicochemical Properties