Odd-numbered fullerene fragment ions from C[sub 60] oxides

Journal Article · Thu Nov 11 04:00:00 EST 1993 · Journal of Physical Chemistry; (United States)

DOI:https://doi.org/10.1021/j100147a002· OSTI ID:5424450

Deng, J P; Ju, D D; Her, G R; Mou, C Y ^[1]; Chen, C J; Lin, Y Y ^[2]; Han, C C ^[3]

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1. National Taiwan Univ., Taipei (Taiwan, Province of China)
2. National Chung Hsing Univ., Taichung (Taiwan, Province of China)
3. Academia Sinica, Taipei (Taiwan, Province of China)

Odd-numbered carbon-only anion clusters, C[sub 53]-, C[sub 55]-, C[sub 57]-, and C[sub 59]-, are observed in laser desorption ionization of C[sub 60]O obtained in reactions of C[sub 60] with O[sub 3]. These odd-numbered carbon clusters are suggestive of the presence of the ether form monoxide resulting from oxygen insertion into the C-C bond shared by adjacent five- and six-membered rings. 18 refs., 4 figs.

• OSTI ID: 5424450
• Journal Information: Journal of Physical Chemistry; (United States), Journal Name: Journal of Physical Chemistry; (United States) Vol. 97:45; ISSN JPCHAX; ISSN 0022-3654
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400102 -- Chemical & Spectral Procedures
400201* -- Chemical & Physicochemical Properties
400500 -- Photochemistry
ALKYLATED AROMATICS
AROMATICS
CARBON
CHARGED PARTICLES
CHEMICAL REACTIONS
CHROMATOGRAPHY
DESORPTION
ELECTROMAGNETIC RADIATION
ELEMENTS
FULLERENES
HYDROCARBONS
IONIZATION
IONS
LASER RADIATION
MASS SPECTROSCOPY
NONMETALS
ORGANIC COMPOUNDS
OZONE
RADIATIONS
SEPARATION PROCESSES
SORPTION
SPECTROSCOPY
TOLUENE