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Title: New molecular precursors for low-temperature routes to new oxide materials. Final progress report

Abstract

In this grant period, the authors have explored the single-source precursor route to silicate materials containing various main group and transition metals. They have also explored the development of polymeric precursors to zinc silicate materials. In addition, they have begun to examine precursors for phosphate materials, based on the di(tert-butyl)phosphate ligand, {minus}O{sub 2}P(O{sup t}Bu){sub 2}. A primary focus of these studies is the development of molecular precursors to homogeneous, ultrapure metal silicates and phosphates. More recently, the authors have attempted to develop template-assisted network-forming reactions that could lead to micro- or mesoporous materials. Findings are summarized below for Zr and HF systems, Al systems, Cr systems, Cu systems, metal phosphate precursors, zinc silicate luminescent materials, and syntheses of inorganic materials using dendrimeric polymers as templates.

Authors:
Publication Date:
Research Org.:
California Univ., San Diego, CA (United States)
Sponsoring Org.:
USDOE Office of Energy Research, Washington, DC (United States)
OSTI Identifier:
541801
Report Number(s):
DOE/ER/14272-T2
ON: DE98000722; TRN: AHC29723%%19
DOE Contract Number:  
FG03-92ER14272
Resource Type:
Technical Report
Resource Relation:
Other Information: PBD: [1997]
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; SILICATES; PHOSPHATES; PRECURSOR; PROGRESS REPORT; SYNTHESIS; ZIRCONIUM SILICATES; HAFNIUM SILICATES; ALUMINIUM SILICATES; CHROMIUM SILICATES; COPPER SILICATES; ZIRCONIUM PHOSPHATES; ZINC SILICATES; CATALYSTS

Citation Formats

Tilley, T D. New molecular precursors for low-temperature routes to new oxide materials. Final progress report. United States: N. p., 1997. Web. doi:10.2172/541801.
Tilley, T D. New molecular precursors for low-temperature routes to new oxide materials. Final progress report. United States. doi:10.2172/541801.
Tilley, T D. Wed . "New molecular precursors for low-temperature routes to new oxide materials. Final progress report". United States. doi:10.2172/541801. https://www.osti.gov/servlets/purl/541801.
@article{osti_541801,
title = {New molecular precursors for low-temperature routes to new oxide materials. Final progress report},
author = {Tilley, T D},
abstractNote = {In this grant period, the authors have explored the single-source precursor route to silicate materials containing various main group and transition metals. They have also explored the development of polymeric precursors to zinc silicate materials. In addition, they have begun to examine precursors for phosphate materials, based on the di(tert-butyl)phosphate ligand, {minus}O{sub 2}P(O{sup t}Bu){sub 2}. A primary focus of these studies is the development of molecular precursors to homogeneous, ultrapure metal silicates and phosphates. More recently, the authors have attempted to develop template-assisted network-forming reactions that could lead to micro- or mesoporous materials. Findings are summarized below for Zr and HF systems, Al systems, Cr systems, Cu systems, metal phosphate precursors, zinc silicate luminescent materials, and syntheses of inorganic materials using dendrimeric polymers as templates.},
doi = {10.2172/541801},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1997},
month = {10}
}