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Tritium permeation through clean Incoloy 800 and Sanicro 31 alloys and through steam oxidized Incoloy 800

Journal Article · · Metall. Trans., A; (United States)
DOI:https://doi.org/10.1007/BF02661206· OSTI ID:5408904

The tritium permeabilities, DK, of Incoloy 800 and Sanicro 31 have been determined for tube samples that were protected from surface oxidation by electroplated nickel. The permeabilities of these analogous alloys over the 400 to 750/sup 0/C range were essentially equal; DK = 0.566 exp (-16120/RT) and 0.367 exp (-15610/RT cm/sup 3/ (T/sub 2/.STP).mm/(cm/sup 2/.min.torr/sup 1/2/), respectively. The effects of in-situ steam oxidation of Incoloy 800 were observed to reduce tritium permeabilities by factors up to 400 at 150 days. Permeabilities of the oxides formed at 520, 660 and 725/sup 0/C were determined to be 5.4 E-11, 4.9 E-10 and 2.4 E-9 cc (T/sub 2/, STP) .mm/(cm/sup 2/.min.torr/sup 1/2/), respectively. Severe thermal shock was observed to essentially destroy the permeation barrier characteristics of the oxide coatings while mild temperature cycling had no observable effects on permeation rates through the oxide coated material.

OSTI ID:
5408904
Journal Information:
Metall. Trans., A; (United States), Journal Name: Metall. Trans., A; (United States) Vol. 11:5; ISSN MTTAB
Country of Publication:
United States
Language:
English