Analysis of the vibrational frequencies of the UO/sup 2 +//sub 2/ ion in complexes containing acido-ligands

Journal Article · Sat Feb 01 00:00:00 EST 1986 · J. Appl. Spectrosc. (Engl. Transl.); (United States)

OSTI ID:5399563

Kobets, L V; Umreiko, D S

This paper presents an analysis of the vibrational frequencies of the UO/sup 2 +//sub 2/ ion in its complexes with acido-ligands that shows that in the series of the compounds indicated the correlation of UO/sup 2 +//sub 2/ with the nature of the anions and in particular with their basicity is limited in nature and may not be considered without taking account of the specific structures. If neutral ligands are present in the complexes, the situation is probably even more complicated.

• OSTI ID: 5399563
• Journal Information: J. Appl. Spectrosc. (Engl. Transl.); (United States), Vol. 43:2
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
LIGANDS
BINDING ENERGY
URANYL COMPLEXES
URANYL COMPOUNDS
LATTICE VIBRATIONS
ABSORPTION SPECTRA
CHEMICAL COMPOSITION
COMPLEXOMETRY
CONFIGURATION INTERACTION
COORDINATION NUMBER
COORDINATION VALENCES
INFRARED SPECTRA
PH VALUE
RUBIDIUM COMPLEXES
URANYL CHLORIDES
URANYL FLUORIDES
ACTINIDE COMPLEXES
ACTINIDE COMPOUNDS
ALKALI METAL COMPLEXES
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
ENERGY
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
SPECTRA
URANIUM COMPLEXES
URANIUM COMPOUNDS
VALENCE
400104* - Spectral Procedures- (-1987)
400201 - Chemical & Physicochemical Properties