Potassium perchlorate reaction with pyrotechnic fuels

Conference · Sat Jan 01 04:00:00 EST 1983

OSTI ID:5396071

Wang, P S; Moddeman, W E; Bowling, W C

Surface sensitive x-ray photoelectron spectroscopy (XPS) and x-ray induced Auger electron spectroscopy (XAES) were used to analyze surface changes in Fe/KC10/sub 4/, TiH/sub 0.65//KC10/sub 4/ and Al foils in KC10/sub 4/ during accelerated aging at 60 and 120/sup 0/C. The result shows a 0.02% Cl/sup -/ formation per day in Fe/KC10/sub 4/ and TiH/sub 0.65//KC10/sub 4/ powders aged at 120/sup 0/C for less than or equal to 145 days. No KC10/sub 4/ decomposition was observed under the similar aging conditions in KC10/sub 4/ samples without pyrotechnic fuels. Titanium oxide to KC10/sub 4/ signal ratio in a pressed disk of TiH/sub 0.65//KC10/sub 4/ was found to be lower than that of the powdered samples. Carbon impurities were noted in all powders, especially strong in metal (or subhydride) containing specimens; carbon impurities were slightly removed from the subhydride during aging.

• Research Organization: Monsanto Research Corp., Miamisburg, OH (USA). Mound
• DOE Contract Number: AC04-76DP00053
• OSTI ID: 5396071
• Report Number(s): MLM-3117-OP; CONF-8310111-9; ON: DE84002840
• Country of Publication: United States
• Language: English

Related Subjects

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEFENSE
450100* -- Military Technology
Weaponry
& National Defense-- Chemical Explosions & Explosives
AGING
ALKALI METAL COMPOUNDS
ALUMINIUM
AUGER ELECTRON SPECTROSCOPY
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
DECOMPOSITION
ELECTRON SPECTROSCOPY
ELEMENTS
HALIDES
HALOGEN COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
IRON
METALS
OXIDIZERS
OXYGEN COMPOUNDS
PERCHLORATES
PHOTOELECTRON SPECTROSCOPY
POTASSIUM COMPOUNDS
POTASSIUM PERCHLORATES
PYROTECHNIC DEVICES
SPECTROSCOPY
STABILITY
SURFACES
TITANIUM COMPOUNDS
TITANIUM HYDRIDES
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS