The role of basic aluminum sulfate minerals in controlling sulfate retention in the mineral horizons of two spodosols

Journal Article · Sat Sep 01 04:00:00 EDT 1990 · Soil Science; (United States)

DOI:https://doi.org/10.1097/00010694-199009000-00002· OSTI ID:5395993

Courchesne, F ^[1]; Hendershot, W H ^[2]

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1. Univ. of Montreal, Quebec (Canada)
2. McGill Univ., Ste-Anne de Bellevue, Quebec (Canada)

The authors collected soil solutions during the spring snowmelt at two depths using tension-free lysimeters in two Humic Cryorthods located in forested catchments. They also extracted soil solutions by centrifugation from the B and the C horizons of these soils. Although most data points cluster around the solubility line of natural gibbsite, the relationship between Al{sup 3+} activity and solution pH showed a marked departure from Al(OH){sub 3} solubility with a slope of {minus}1.91. Moreover, at pH values below 4.6, solutions were slightly undersaturated with respect to natural gibbsite. Results from thermodynamic calculations suggested that the Hermine B, and probably the Coniferous B, horizons have attained chemical conditions sufficient to enter the stability field of a basic aluminum sulfate mineral formed in the presence of Al(OH){sub 3}. Mineral stability relationships indicated that the solid phase of concern could be alunite (pK{sub s} = 85.4) and that the apparent saturation status of the soil solutions with respect to alunite increased with increasing reaction time. However, physical evidence for the presence of alunite in these horizons is still lacking. Solutions from the C horizons were all clearly undersaturated with respect to any Al{sub x}(OH){sub y}(SO{sub 4}){sub z} mineral. While the possible formation of alunite could be affecting sulfate retention in these acid soils, the results do not exclude the pH-dependent sulfate adsorption mechanism proposed by a number of investigators.

• OSTI ID: 5395993
• Journal Information: Soil Science; (United States), Journal Name: Soil Science; (United States) Vol. 150:3; ISSN SOSCA; ISSN 0038-075X
• Country of Publication: United States
• Language: English

Related Subjects

54 ENVIRONMENTAL SCIENCES
540220* -- Environment
Terrestrial-- Chemicals Monitoring & Transport-- (1990-)
ACIDIFICATION
ALUMINIUM COMPOUNDS
ALUMINIUM SULFATES
CHEMISTRY
OXYGEN COMPOUNDS
PH VALUE
RETENTION
SOIL CHEMISTRY
SOILS
SOLUBILITY
SULFATES
SULFUR COMPOUNDS
THERMODYNAMICS