Synthesis of substituted derivatives of poly(m-xylylene)
Conference
·
OSTI ID:539052
- Hope College, Holland, MI (United States)
- Oak Ridge National Lab., TN (United States)
A series of new poly(m-xylylene) polymers has been synthesized as model compounds for low-rank coal. These polymers were prepared by the phenyllithium promoted coupling of {alpha},{alpha}{prime}-dibromo-m-xylene and {alpha},{alpha}{prime},5-tribromo-m-xylene in THF. The polymeric product (1) was then converted to a polycarboxylic acid (II) by metalation of the aryl bromide with n-butyllithium and reaction of the polyaryllithium with CO{sub 2}. The synthesis and characterization of these polymers will be discussed.
- OSTI ID:
- 539052
- Report Number(s):
- CONF-960807--
- Country of Publication:
- United States
- Language:
- English
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