Experimental study and kinetic modeling of propene oxidation in a jet stirred flow reactor

Journal Article · Thu Feb 11 04:00:00 EST 1988 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100314a019· OSTI ID:5388130

Dagaut, P; Cathonnet, M; Boettner, J C

The oxidation of propene was studied in a jet stirred flow reactor in the temperature range 900-1200 K at pressures extending from 1 to 8 atm for a wide range of fuel-oxygen equivalence ratios (0.15-4.0). A computer program has been developed to model the experimental data by using a chemical kinetic reaction mechanism. A direct method to determine the first-order sensitivities of the mole fraction of each species with respect to the rate constants was used to develop the kinetic scheme. The present chemical kinetic reaction mechanism is able to reproduce the experimental results, although some discrepancies are observed for the minor products.

• Research Organization: CNRS, Orleans (France)
• OSTI ID: 5388130
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 92:3; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400800 -- Combustion
Pyrolysis
& High-Temperature Chemistry
ALKANES
ALKENES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMICAL REACTORS
DATA
DECOMPOSITION
EXPERIMENTAL DATA
HIGH TEMPERATURE
HYDROCARBONS
INFORMATION
JETS
KINETICS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXIDATION
PROPANE
PROPYLENE
PYROLYSIS
QUANTITY RATIO
REACTION KINETICS
THERMOCHEMICAL PROCESSES
VERY HIGH TEMPERATURE