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Reactivity differences between PO/sub 4//sup 3 -/ and HPO/sub 4//sup 2 -/ ions in oxygen and potassium peroxydiphosphate formation at the platinum

Journal Article · · Sov. Electrochem. (Engl. Transl.); (United States)
OSTI ID:5387284
; ; ; ;
The paper generalizes results obtained in comprehensive kinetic studies of oxygen and peroxydiphosphate formation at platinum in the electrolysis of K/sub 3/PO/sub 4/ and K/sub 2/HPO/sub 4/ solutions with KCl, KSCN, Na/sub 2/SO/sub 3/, (NH/sub 2/)/sub 2/CS, and (NH/sub 2/)/sub 2/CO as additives. The reactivity differences between the PO/sup 3 -/ and HPO/sub 4//sup 2 -/ ions in the two anodic reactions were made apparent. The results were compared with those obtained previously with added KF.
Research Organization:
L. Ya. Karpov Physicochemical Scientific-Research Institute, Moscow (USSR)
OSTI ID:
5387284
Journal Information:
Sov. Electrochem. (Engl. Transl.); (United States), Journal Name: Sov. Electrochem. (Engl. Transl.); (United States) Vol. 23:2; ISSN SOECA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400400* -- Electrochemistry
400700 -- Radiochemistry & Nuclear Chemistry
ACID PHOSPHATES
ALKALI METAL COMPOUNDS
AMMONIUM CARBONATES
AMMONIUM COMPOUNDS
ANTITHYROID DRUGS
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
CARBON COMPOUNDS
CARBONATES
CARBONIC ACID DERIVATIVES
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHLORIDES
CHLORINE COMPOUNDS
DAYS LIVING RADIOISOTOPES
DRUGS
ELECTROCATALYSTS
ELECTROLYSIS
ELECTROLYTES
ELEMENTS
EVEN-EVEN NUCLEI
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HORMONE ANTAGONISTS
ISOTOPE APPLICATIONS
ISOTOPES
KINETICS
LABELLED COMPOUNDS
LIGHT NUCLEI
LYSIS
MATERIALS TESTING
METALS
NONMETALS
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXYGEN
OXYGEN 18
OXYGEN COMPOUNDS
OXYGEN ISOTOPES
PEROXIDES
PHOSPHATES
PHOSPHORUS 32
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
PLATINUM
PLATINUM METALS
POTASSIUM CHLORIDES
POTASSIUM COMPOUNDS
POTASSIUM FLUORIDES
POTASSIUM PHOSPHATES
POTENTIOMETRY
RADIOISOTOPES
REACTION KINETICS
SODIUM COMPOUNDS
SODIUM SULFATES
STABILITY
STABLE ISOTOPES
SULFATES
SULFUR COMPOUNDS
SYNTHESIS
TESTING
THIOCYANATES
TITRATION
TRACER TECHNIQUES
TRANSITION ELEMENTS
YIELDS