Production of uranium dioxide
A continuous, four stage fluidized bed process for converting uranium hexafluoride (UF/sub 6/) to ceramic-grade uranium dioxide (UO/sub 2/) powder suitable for use in the manufacture of fuel pellets for nuclear reactors is disclosed. The process comprises the steps of first reacting UF/sub 6/ with steam in a first fluidized bed, preferably at about 550/sup 0/C, to form solid intermediate reaction products UO/sub 2/F/sub 2/, U/sub 3/O/sub 8/ and an off-gas including hydrogen fluoride (HF). The solid intermediate reaction products are conveyed to a second fluidized bed reactor at which the mol fraction of HF is controlled at low levels in order to prevent the formation of uranium tetrafluoride (UF/sub 4/). The first intermediate reaction products are reacted in the second fluidized bed with steam and hydrogen at a temperature of about 630/sup 0/C. The second intermediate reaction product including uranium dioxide (UO/sub 2/) is conveyed to a third fluidized bed reactor and reacted with additional steam and hydrogen at a temperature of about 650/sup 0/C producing a reaction product consisting essentially of uranium dioxide having an oxygen-uranium ratio of about 2 and a low residual fluoride content. This product is then conveyed to a fourth fluidized bed wherein a mixture of air and preheated nitrogen is introduced in order to further reduce the fluoride content of the UO/sub 2/ and increase the oxygen-uranium ratio to about 2.25.
- Assignee:
- Westinghouse Electric Corp.
- Patent Number(s):
- US 4053559
- Application Number:
- TRN: 78-002511
- OSTI ID:
- 5386597
- Resource Relation:
- Patent File Date: Filed date 14 Jun 1976
- Country of Publication:
- United States
- Language:
- English
Similar Records
CHEMICAL ENGINEERING DIVISION SUMMARY REPORT FOR APRIL, MAY, JUNE 1960
PREPARATION OF DENSE URANIUM DIOXIDE PARTICLES FROM URANIUM HEXAFLUORIDE IN A FLUIDIZED BED
Related Subjects
36 MATERIALS SCIENCE
URANIUM DIOXIDE
PRODUCTION
CONVERSION
FLUIDIZED BED
HYDROGEN
REDUCTION
STEAM
URANIUM HEXAFLUORIDE
ACTINIDE COMPOUNDS
CHALCOGENIDES
CHEMICAL REACTIONS
CRYOGENIC FLUIDS
ELEMENTS
FLUIDS
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
NONMETALS
OXIDES
OXYGEN COMPOUNDS
URANIUM COMPOUNDS
URANIUM FLUORIDES
URANIUM OXIDES
050400* - Nuclear Fuels- Feed Processing
360201 - Ceramics
Cermets
& Refractories- Preparation & Fabrication