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Title: Hydrocarbon synthesis catalyst and method of preparation and use thereof. [DOE patent application]

Abstract

A catalyst for the synthesis of hydrocarbons from carbon monoxide and hydrogen composed of palladium or platinum and cobalt supported on a solid phase is disclosed. The catalyst is prepared by heating a heterogeneous component of the palladium or platinum deposited on the solid support in a solution of cobalt carbonyl or precursors thereof. The catalyst exhibits excellent activity, stability in air, and produces highly desirable product fractions even with dilute gaseous reactants. The catalyst is preferably used in dilute slurry form, which is desirable from a heat transfer standpoint.

Inventors:
; ;
Publication Date:
OSTI Identifier:
5383902
Application Number:
ON: DE82013607
Assignee:
Dept. of Energy
DOE Contract Number:  
AC02-76CH00016
Resource Type:
Patent
Resource Relation:
Other Information: Portions of document are illegible
Country of Publication:
United States
Language:
English
Subject:
01 COAL, LIGNITE, AND PEAT; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ALUMINIUM OXIDES; CATALYTIC EFFECTS; SYNTHESIS; CATALYSTS; COBALT COMPLEXES; FISCHER-TROPSCH SYNTHESIS; PALLADIUM; PLATINUM; CARBON MONOXIDE; CARBONYLS; CATALYST SUPPORTS; COMPARATIVE EVALUATIONS; EXPERIMENTAL DATA; GAS CHROMATOGRAPHY; HYDROGENATION; ALUMINIUM COMPOUNDS; CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; CHEMICAL REACTIONS; CHROMATOGRAPHY; COMPLEXES; DATA; ELEMENTS; INFORMATION; METALS; NUMERICAL DATA; OXIDES; OXYGEN COMPOUNDS; PLATINUM METALS; SEPARATION PROCESSES; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENTS; 010405* - Coal, Lignite, & Peat- Hydrogenation & Liquefaction; 400201 - Chemical & Physicochemical Properties; 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)

Citation Formats

Sapienza, R. S., Sansone, M. J., and Slegeir, W. A.R. Hydrocarbon synthesis catalyst and method of preparation and use thereof. [DOE patent application]. United States: N. p., 1981. Web.
Sapienza, R. S., Sansone, M. J., & Slegeir, W. A.R. Hydrocarbon synthesis catalyst and method of preparation and use thereof. [DOE patent application]. United States.
Sapienza, R. S., Sansone, M. J., and Slegeir, W. A.R. Fri . "Hydrocarbon synthesis catalyst and method of preparation and use thereof. [DOE patent application]". United States. https://www.osti.gov/servlets/purl/5383902.
@article{osti_5383902,
title = {Hydrocarbon synthesis catalyst and method of preparation and use thereof. [DOE patent application]},
author = {Sapienza, R. S. and Sansone, M. J. and Slegeir, W. A.R.},
abstractNote = {A catalyst for the synthesis of hydrocarbons from carbon monoxide and hydrogen composed of palladium or platinum and cobalt supported on a solid phase is disclosed. The catalyst is prepared by heating a heterogeneous component of the palladium or platinum deposited on the solid support in a solution of cobalt carbonyl or precursors thereof. The catalyst exhibits excellent activity, stability in air, and produces highly desirable product fractions even with dilute gaseous reactants. The catalyst is preferably used in dilute slurry form, which is desirable from a heat transfer standpoint.},
doi = {},
url = {https://www.osti.gov/biblio/5383902}, journal = {},
number = ,
volume = ,
place = {United States},
year = {1981},
month = {8}
}