Infrared chemiluminescence study of the F atom + HMn(CO)/sub 5/ reaction

Journal Article · Thu Jan 14 04:00:00 EST 1988 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100312a001· OSTI ID:5371757

Wategaonkar, S J; Setser, D W

The HF infrared chemiluminescence from the reaction of F atoms with HMn(CO)/sub 5/ has been observed in a flow reactor. The nascent HF vibrational distribution is P/sub 1/-P/sub 4/ = 0.20:0.44:0.35: approx. 0.01, and is 0.31 for P/sub 0/ assigned to zero. The HF(v,J) populations do not extend to the thermochemical limit, and is abnormally low relative to typical H abstraction reaction by F atoms. The H abstraction reaction from toluene-d/sub 5/ was reinvestigated to provide a reference for a system yielding HF(v) and a product with a large radical stabilization energy. The D/sub 0/(CH/sub 3/C/sub 6/D/sub 4/-D) was estimated asless than or equal to 115.3 kcal mol/sup -1/, based upon the highest observed DF(v,J) level.

• Research Organization: Kansas State Univ., Manhattan
• OSTI ID: 5371757
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 92:1; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400500 -- Photochemistry
ALKYLATED AROMATICS
AROMATICS
CARBONYLS
CHEMICAL REACTIONS
CHEMICAL REACTORS
CHEMILUMINESCENCE
DATA
DEUTERIUM COMPOUNDS
ELEMENTS
EMISSION SPECTROSCOPY
EXPERIMENTAL DATA
FLUORINE
HALOGENS
HYDROCARBONS
HYDROGEN COMPOUNDS
INFORMATION
LUMINESCENCE
MANGANESE COMPOUNDS
NONMETALS
NUMERICAL DATA
ORGANIC COMPOUNDS
SPECTROSCOPY
TOLUENE
TRANSITION ELEMENT COMPOUNDS