Syntheses and phosphorus-31 NMR studies of five-coordinate platinum(II) complexes of tris(2-(diphenylphosphino)ethyl)phosphine and monodentate phosphorus ligands
Journal Article
·
· Inorg. Chem.; (United States)
The first preparation and characterization of the platinum (II) complexes containing five phosphorus ligands are reported herein. The complexes are represented by the formulae (Pt(PP/sub 3/)(P(OR)/sub 3/)Cl/sub 2/, where R = Me or Et, and (Pt(PP/sub 3/)(PEt/sub 3/))Cl/sub 2/. The /sup 31/P spectra of the complexes are presented. 10 references, 2 tables.
- Research Organization:
- Universitaet Innsbruck, Austria
- OSTI ID:
- 5371567
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 26:24; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Syntheses and characterization of trigonal-bipyramidal rhodium(I) complexes of tris(2-(diphenylphosphino)ethyl) phosphine and determination of a spectroscopic trans-influence series by sup 31 P ( sup 1 H) NMR spectroscopy
Phosphato complexes of platinum(II): Phosphorus-31 NMR and kinetics of formation and isomerization studies
Bonding mode variations in palladium(II) and platinum(II) azaphosphole complexes: Identification by /sup 1/H, /sup 31/P, and /sup 195/Pt (NMR of N- and P-coordination, Pt-Cl addition to P, and dimerization
Journal Article
·
Tue Oct 31 23:00:00 EST 1989
· Inorganic Chemistry; (USA)
·
OSTI ID:6971410
Phosphato complexes of platinum(II): Phosphorus-31 NMR and kinetics of formation and isomerization studies
Journal Article
·
Wed Sep 05 00:00:00 EDT 1990
· Inorganic Chemistry; (USA)
·
OSTI ID:6170545
Bonding mode variations in palladium(II) and platinum(II) azaphosphole complexes: Identification by /sup 1/H, /sup 31/P, and /sup 195/Pt (NMR of N- and P-coordination, Pt-Cl addition to P, and dimerization
Journal Article
·
Wed Jul 27 00:00:00 EDT 1988
· Inorg. Chem.; (United States)
·
OSTI ID:5708306
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
ALKANES
CHEMICAL PREPARATION
CHLORIDES
CHLORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
ISOTOPES
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
PLATINUM CHLORIDES
PLATINUM COMPOUNDS
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
ALKANES
CHEMICAL PREPARATION
CHLORIDES
CHLORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
ISOTOPES
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
PLATINUM CHLORIDES
PLATINUM COMPOUNDS
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS