Extraction chemistry of fermentation product carboxylic acid
Within the framework of a program aiming to improve the existing extractive recovery technology of fermentation products, the state of the art is critically reviewed. The acids under consideration are propionic, lactic, pyruvic, succinic, fumaric, maleic, malic, itaconic, tartaric, citric, and isocitric, all obtained by the aerobic fermentation of glucose via the glycolytic pathway and glyoxylate bypass. With no exception, it is the undissociated monomeric acid that is extracted into carbon-bonded and phosphorus-bonded oxygen donor extractants. In the organic phase, the acids are usually dimerized. The extractive transfer process obeys the Nernst law, and the measured partition coefficients range from about 0.003 for aliphatic hydrocarbons to about 2 to 3 for aliphatic alcohols and ketones to about 10 or more for organophosphates. Equally high distribution ratios are measured when long-chain tertiary amines are employed as extractants, forming bulky salts preferentially soluble in the organic phase. 123 references.
- Research Organization:
- Univ. of California, Berkeley
- OSTI ID:
- 5367280
- Journal Information:
- Biotechnol. Bioeng.; (United States), Journal Name: Biotechnol. Bioeng.; (United States) Vol. 28:2; ISSN BIBIA
- Country of Publication:
- United States
- Language:
- English
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AEROBIC CONDITIONS
ALCOHOLS
ALDEHYDES
BIOCONVERSION
CARBOHYDRATES
CARBOXYLIC ACIDS
CHEMISTRY
CITRIC ACID
DICARBOXYLIC ACIDS
EXTRACTION
FERMENTATION
GLUCOSE
HEXOSES
HYDROXY ACIDS
HYDROXY COMPOUNDS
ITACONIC ACID
KETO ACIDS
KETONES
LACTIC ACID
MALEIC ACID
MANAGEMENT
MATERIALS RECOVERY
MONOCARBOXYLIC ACIDS
MONOSACCHARIDES
ORGANIC ACIDS
ORGANIC COMPOUNDS
PROCESSING
PROPIONIC ACID
PYRUVIC ACID
RECOVERY
SACCHARIDES
SEPARATION PROCESSES
WASTE MANAGEMENT
WASTE PROCESSING