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U.S. Department of Energy
Office of Scientific and Technical Information

Chemistry of acid strip-mine lake recovery

Book ·
OSTI ID:5360339
A study of the role of metals from the time of acid formation on the pyrite crystal to the time of lake recovery focused on 12 lakes northeast of Columbia, Missouri to determine iron-clay-aluminum interaction. The high concentration of aluminum and iron make the greatest contribution to the net buffer capacity of the water, and is responsible for the long natural recovery times associated with all acid strip-mine lakes. The amount of aluminum dissolved and allowed to flow into the lake depends upon the clay type and minerals dissolved on the spoil banks. The longer the lake remains at low pH values, the more difficult it is for the sulfate reducing bacteria to maintain growth and reproduce. The bacteria slowly titrate the acidity through the release of hydrogen sulfide to the atmosphere until all acidic buffers below 4.5 are exhausted. At this point lake recovery proceeds at a rapid rate. 21 references, 27 figures, 5 tables.
Research Organization:
Department of the Interior, Washington, DC (USA)
OSTI ID:
5360339
Country of Publication:
United States
Language:
English