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Title: Alkylation of organic aromatic compounds

Abstract

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 figures.

Inventors:
; ;
Publication Date:
OSTI Identifier:
5356138
Patent Number(s):
US 5243115; A
Application Number:
PPN: US 7-690373
Assignee:
Chemical Research and Licensing Co., Pasadena, CA (United States) PTO; EDB-94-046449
DOE Contract Number:  
FC07-80CS40454
Resource Type:
Patent
Resource Relation:
Patent File Date: 22 Apr 1991
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; AROMATICS; ALKYLATION; ALKENES; ALKYLATED AROMATICS; DISTILLATION EQUIPMENT; PRESSURIZATION; SYNTHESIS; CHEMICAL REACTIONS; EQUIPMENT; HYDROCARBONS; ORGANIC COMPOUNDS; 400201* - Chemical & Physicochemical Properties

Citation Formats

Smith, L.A. Jr., Arganbright, R.P., and Hearn, D.. Alkylation of organic aromatic compounds. United States: N. p., 1993. Web.
Smith, L.A. Jr., Arganbright, R.P., & Hearn, D.. Alkylation of organic aromatic compounds. United States.
Smith, L.A. Jr., Arganbright, R.P., and Hearn, D.. Tue . "Alkylation of organic aromatic compounds". United States.
@article{osti_5356138,
title = {Alkylation of organic aromatic compounds},
author = {Smith, L.A. Jr. and Arganbright, R.P. and Hearn, D.},
abstractNote = {Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 figures.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Sep 07 00:00:00 EDT 1993},
month = {Tue Sep 07 00:00:00 EDT 1993}
}