Synthesis of organic sulfur compounds by means of silicon-containing reagents
The reaction of alkoxy-, amino-, and thiosilanes with halo (pseudohalo) derivatives of sulfur, as well as the reactions of organosilicon derivatives of hydrogen sulfide, mercaptans, and sulfonic acids with halogen-containing organic compounds proceed via mechanisms of the exchange type; organic derivatives of sulfur and low-boiling silicon compounds (trimethylhalo- and N,N-dimethylaminosilanes and hexamethyldisiloxane) are formed in high yields. These reactions can serve as convenient methods for the preparation of a number of sulfur compounds that are difficult to obtain. Hexamethyldisilthiane can be used as a reducing agent for sulfoxides and sulfines, as well as their selenium analogs.
- Research Organization:
- Lensovet Leningrad Technological Institute (USSR)
- OSTI ID:
- 5355036
- Journal Information:
- J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 56:7; ISSN JGCHA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Characterization of carbon-sulfur bond cleavage by axenic and mixed cultures of Rhodococcus rhodochrous IGTS8
Combined chemical and microbiological removal of organic sulfur from coal
Related Subjects
400201* -- Chemical & Physicochemical Properties
ALKOXIDES
AMINES
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
COMPLEXES
IODINE COMPLEXES
KINETICS
MATERIALS TESTING
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
REACTION KINETICS
SELENIUM COMPLEXES
SILICON COMPLEXES
SYNTHESIS
TELLURIUM COMPLEXES
TESTING