Synthesis of cyclopropyl sulfides and cyclopropyl sulfones by sulfenylchlorination of 3,3-disubstituted cyclopropenes

Journal Article · Wed Sep 10 00:00:00 EDT 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5354784

Gritsenko, E I; Butenko, G G; Plemenkov, V V; Balueva, A I; Bolesov, I G

This work shows the results of an NMR investigation of reactions of 3,3-dimethylcyclopropene, 3-methyl-3-phenylcyclopropene, and 3-methyl-3-cyanocyclopropene with methylsulfenyl chloride, ethylsulfenyl chloride, and phenylsulfenyl chloride. It has been found that sulfenyl halides easily form adducts with cyclopropenes even at -20 to -50/sup 0/C.ctivity

• Research Organization: V. I. Ul'yanov-Lenin Kazan State Univ. (USSR)
• OSTI ID: 5354784
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 56:3; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ADDUCTS
ALKENES
ATOMIC MODELS
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINATION
CONFIGURATION INTERACTION
COUPLING
COUPLING CONSTANTS
CYCLOALKENES
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATION
HYDROCARBONS
INTERMEDIATE COUPLING
ISOMERIZATION
ISOMERS
J-J COUPLING
MATHEMATICAL MODELS
MECHANICS
MOLECULAR STRUCTURE
NMR SPECTRA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC SOLVENTS
ORGANIC SULFUR COMPOUNDS
PROPYLENE
QUANTUM MECHANICS
SOLVENT PROPERTIES
SOLVENTS
SPECTRA
STEREOCHEMISTRY
SULFIDES
SULFOCHLORINATION
SULFONATION
SULFONES
SULFUR COMPOUNDS