Formation of 1-silacyclopenta-2,4-diene through recoil silicon atom reactions
Journal Article
·
· J. Am. Chem. Soc.; (United States)
(/sup 31/Si)-1-silacyclopenta-2,4-diene was prepared through the reactions of recoil silicon-31 atoms with butadiene. Its identification was verified by the fact that it was catalytically hydrogenated to (/sup 31/Si)-1-silacyclopent-3-ene. (/sup 31/Si)-1-Silacyclopenta-2,4-diene is sensitive to ..gamma..-ray irradiation. It is also thermally unstable at a temperature higher than 100/sup 0/C. Possible mechanisms for its formation are considered. 5 figures, 1 table.
- Research Organization:
- Texas A and M Univ., College Station
- OSTI ID:
- 5345076
- Journal Information:
- J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 102:7; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400701* -- Radiochemistry & Nuclear Chemistry-- Hot-Atom Chemistry
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
BUTADIENE
CHEMISTRY
DIENES
ELECTROMAGNETIC RADIATION
EVEN-ODD NUCLEI
GAMMA RADIATION
HOT ATOM CHEMISTRY
HOURS LIVING RADIOISOTOPES
HYDROCARBONS
IONIZING RADIATIONS
ISOTOPES
LIGHT NUCLEI
MEDIUM TEMPERATURE
NUCLEI
ORGANIC COMPOUNDS
PHYSICAL PROPERTIES
POLYENES
RADIATIONS
RADIOCHEMISTRY
RADIOISOTOPES
RECOILS
SILICON 31
SILICON COMPOUNDS
SILICON ISOTOPES
SYNTHESIS
THERMODYNAMIC PROPERTIES
400701* -- Radiochemistry & Nuclear Chemistry-- Hot-Atom Chemistry
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
BUTADIENE
CHEMISTRY
DIENES
ELECTROMAGNETIC RADIATION
EVEN-ODD NUCLEI
GAMMA RADIATION
HOT ATOM CHEMISTRY
HOURS LIVING RADIOISOTOPES
HYDROCARBONS
IONIZING RADIATIONS
ISOTOPES
LIGHT NUCLEI
MEDIUM TEMPERATURE
NUCLEI
ORGANIC COMPOUNDS
PHYSICAL PROPERTIES
POLYENES
RADIATIONS
RADIOCHEMISTRY
RADIOISOTOPES
RECOILS
SILICON 31
SILICON COMPOUNDS
SILICON ISOTOPES
SYNTHESIS
THERMODYNAMIC PROPERTIES