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Pressure-volume-temperature properties of aqueous mixed electrolyte solutions: NaCl + BaCl[sub 2] from 25 to 140[degree]C

Journal Article · · Journal of Chemical and Engineering Data; (United States)
DOI:https://doi.org/10.1021/je00013a042· OSTI ID:5341667
; ;  [1]
  1. Univ. of Oklahoma, Norman (United States). Dept. of Chemistry
Pressure-volume-temperature (PVT) properties of aqueous mixed electrolyte solutions are useful for many applications in geology, oil recovery, oceanography, and geothermal brines. The densities of aqueous electrolyte mixtures of NaCl + BaCl[sub 2] have been measured from 25 to 140 C at constant total ionic strengths of 0.5, 1.0, 2.5, and 4.5 mol. The mean apparent molal volumes calculated from the experimental density values have been treated using the Pitzer equations, and the ion interaction parameters of mixing have been evaluated. The required apparent molal volumes for the pure aqueous BaCl[sub 2] and NaCl have been obtained from the earlier work and that of Rogers and Pitzer, respectively.
OSTI ID:
5341667
Journal Information:
Journal of Chemical and Engineering Data; (United States), Journal Name: Journal of Chemical and Engineering Data; (United States) Vol. 39:1; ISSN JCEAAX; ISSN 0021-9568
Country of Publication:
United States
Language:
English