Hydrogenolysis of isobutane on iridium
Technical Report
·
OSTI ID:5340585
The hydrogenolysis of isobutane on iridium has been investigated ovetr the pressure range 0 to 100 torr. The iridium catalyst is a 48.5 A thick film vapor deposited on the inside of a round bottom flask under ultra high vacuum conditions. Methane was observed to be the only reaction product. Adsorption experiments indicate competitive adsorption to occur for hydrogen and hydrocarbon with respect to the iridium.
- Research Organization:
- Ames Lab., IA (USA)
- DOE Contract Number:
- W-7405-ENG-82
- OSTI ID:
- 5340585
- Report Number(s):
- IS-T-1089; ON: DE84007195
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
090121 -- Hydrocarbon Fuels-- Chemical Synthesis-- (1976-1989)
10 SYNTHETIC FUELS
2-METHYLPROPANE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ADSORPTION
ALKANES
CATALYSTS
CHEMICAL REACTIONS
DESORPTION
ELEMENTS
FILMS
HYDROCARBONS
HYDROGENATION
IRIDIUM
METALS
METHANE
ORGANIC COMPOUNDS
PLATINUM METALS
PRODUCTION
SORPTION
THIN FILMS
TRANSITION ELEMENTS
10 SYNTHETIC FUELS
2-METHYLPROPANE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ADSORPTION
ALKANES
CATALYSTS
CHEMICAL REACTIONS
DESORPTION
ELEMENTS
FILMS
HYDROCARBONS
HYDROGENATION
IRIDIUM
METALS
METHANE
ORGANIC COMPOUNDS
PLATINUM METALS
PRODUCTION
SORPTION
THIN FILMS
TRANSITION ELEMENTS