Reactivity of rhodium and iridium octaethylporphyrin hydrides toward carbon monoxide: thermodynamic studies of the rhodium formyl and iridium hydrido carbonyl complexes
Journal Article
·
· J. Am. Chem. Soc.; (United States)
Iridium octaethylporphyrin hydride, Ir(OEP)(H), reacts with carbon monoxide to form the carbonyl complex Ir(OEP)(H)(CO) at the same conditions where Rh(OEP)(H) reacts with CO to produce the metalloformyl complex Rh-(OEP)(CHO). Thermodynamic studies for these reactions are reported and discussed in terms of differences in the M-H and M-C bond energies and the acceptor properties of the five-coordinate metalloporphyrin hydride complexes.
- Research Organization:
- Univ. of Pennsylvania, Philadelphia
- OSTI ID:
- 5331709
- Journal Information:
- J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 108:13; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
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Journal Article
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Wed Aug 31 00:00:00 EDT 1988
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:5914172
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Wed Sep 01 00:00:00 EDT 1993
· Organometallics; (United States)
·
OSTI ID:5651916
Mixed N-Heterocyclic Carbene-Bis(oxazolinyl)borato Rhodium and Iridium Complexes in Photochemical and Thermal Oxidative Addition Reactions
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Sun Dec 07 23:00:00 EST 2014
· Organometallics
·
OSTI ID:1166702
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBOXYLIC ACIDS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
COMPLEXES
DATA
EXPERIMENTAL DATA
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
INFORMATION
IRIDIUM COMPLEXES
KINETICS
NUMERICAL DATA
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PORPHYRINS
REACTION KINETICS
RHODIUM COMPLEXES
THERMODYNAMICS
TRANSITION ELEMENT COMPLEXES
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBOXYLIC ACIDS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
COMPLEXES
DATA
EXPERIMENTAL DATA
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
INFORMATION
IRIDIUM COMPLEXES
KINETICS
NUMERICAL DATA
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PORPHYRINS
REACTION KINETICS
RHODIUM COMPLEXES
THERMODYNAMICS
TRANSITION ELEMENT COMPLEXES