Photoelectrosynthesis of ethane from acetate ion at an n-type TiO/sub 2/ electrode. The photo-Kolbe reaction
Journal Article
·
· J. Am. Chem. Soc.; (United States)
The photoassisted oxidation of acetate ion to ethane in acetonitrile solutions at n-type TiO/sub 2/ electrodes in both the single-crystal and vapor deposited polycrystalline forms is reported. The quantum efficiency for acetate oxidation was approximately 65 percent at 0 v vs. Ag/0.1 M AgNO/sub 3/ for 0.08 M tetra-n-butylammonium acetate. (JSR)
- Research Organization:
- Univ. of Texas, Austin
- OSTI ID:
- 5324221
- Journal Information:
- J. Am. Chem. Soc.; (United States), Vol. 99:23
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
10 SYNTHETIC FUELS
14 SOLAR ENERGY
ACETATES
PHOTOCHEMICAL REACTIONS
ETHANE
SYNTHESIS
SOLAR ENERGY CONVERSION
TITANIUM OXIDES
CATALYTIC EFFECTS
ELECTROLYTIC CELLS
OXIDATION
ALKANES
CARBOXYLIC ACID SALTS
CHALCOGENIDES
CHEMICAL REACTIONS
CONVERSION
ENERGY CONVERSION
HYDROCARBONS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
TITANIUM COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
090121* - Hydrocarbon Fuels- Chemical Synthesis- (1976-1989)
140505 - Solar Energy Conversion- Photochemical
Photobiological
& Thermochemical Conversion- (1980-)
14 SOLAR ENERGY
ACETATES
PHOTOCHEMICAL REACTIONS
ETHANE
SYNTHESIS
SOLAR ENERGY CONVERSION
TITANIUM OXIDES
CATALYTIC EFFECTS
ELECTROLYTIC CELLS
OXIDATION
ALKANES
CARBOXYLIC ACID SALTS
CHALCOGENIDES
CHEMICAL REACTIONS
CONVERSION
ENERGY CONVERSION
HYDROCARBONS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
TITANIUM COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
090121* - Hydrocarbon Fuels- Chemical Synthesis- (1976-1989)
140505 - Solar Energy Conversion- Photochemical
Photobiological
& Thermochemical Conversion- (1980-)