Solubility of carbon monoxide in 1,4-dioxane

Journal Article · Sat Dec 31 23:00:00 EST 1983 · J. Chem. Eng. Data; (United States)

DOI:https://doi.org/10.1021/je00035a013· OSTI ID:5320164

Veleckis, E; Hacker, D S

The solubility of CO in 1,4-dioxane was determined as a function of pressure (7-70 atm) and temperature (80-173/sup 0/C). An expression is given for solubility that relates the mole fraction and partial pressure of CO (in atmospheres) and the temperature in degrees Kelvin. The results, analyzed in terms of the Krichevsky-Ilinskaya equation, showed that the partial molar volume of CO was independent of pressure and that the isobaric Henry's law was obeyed in the ranges studied. Comparisons with other solvents showed that, on the basis of CO dissolution characteristics, 1,4-dioxane can be classified better with polar than with nonpolar solvents.

• Research Organization: Argonne National Lab., IL
• OSTI ID: 5320164
• Journal Information: J. Chem. Eng. Data; (United States), Journal Name: J. Chem. Eng. Data; (United States) Vol. 29:1; ISSN JCEAA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CHALCOGENIDES
DATA
DIOXANE
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
SOLUBILITY
SOLVENT PROPERTIES