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Overburden analyses by acid-base accounting and simulated weathering studies as a means of determining the probable hydrological consequences of mining and reclamation

Conference · · Univ. Ky., Off. Eng. Serv., (Bull.); (United States)
OSTI ID:5306229
Acid-Base Accounting, selected overburden materials and mixtures of such, both treated and untreated, were placed in simulated weathering columns and leached once a week for a one-year time period. The rocks in the columns were mixed, layered, and/or treated to simulate mixtures, layers, and/or treatments that could be expected in surface mining backfills by modern mining techniques. Acid-Base Accounting predicted the quality of leachate obtained from the columns. Each leachate was analyzed for parameters generally required by state and federal regulations. The parameters include pH, total acidity, total alkalinity, total iron, total manganese, dissolved iron, sulfates, specific conductivity, calcium and magnesium. Initially, the leachate data showed accelerated chemical reactions which tapered off over time. The amounts of pyritic sulfur oxidation and carbonate dissolution were estimated from accumulated concentrations of iron, sulfate, and calcium plus magnesium leached from the columns. Post-leaching acid-base accounting was used to verify the estimates.
OSTI ID:
5306229
Report Number(s):
CONF-821175-
Conference Information:
Journal Name: Univ. Ky., Off. Eng. Serv., (Bull.); (United States)
Country of Publication:
United States
Language:
English