Electrochemical studies of protonated and deprotonated forms of heteroleptic and homoleptic europium{sup (III)} and dysprosium{sup (III)} porphyrin double-deckers
Journal Article
·
· Journal of Coordination Chemistry
- Univ. of Crete (Greece)
- Laboratoire de Chimie de Coordination, Toulouse (France)
Lanthanide {open_quotes}sandwich{close_quotes}-type porphyrins are those with double-decker or triple-decker structures of the form M(por){sub 2} or M{sub 2}(por){sub 3} where (por) is the dianion of the porphyrin ring. The cyclic voltammetric oxidation, of heteroleptic and homoleptic lanthanide porphyrin double-deckers demonstrates the presence of equilibrium protonated/deprotonated species present in CH{sub 2}Cl{sub 2}, DMF, and THF. 20 refs., 3 figs., 2 tabs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 530525
- Journal Information:
- Journal of Coordination Chemistry, Journal Name: Journal of Coordination Chemistry Journal Issue: 1 Vol. 39; ISSN JCCMBQ; ISSN 0095-8972
- Country of Publication:
- United States
- Language:
- English
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