Combined chemical and microbiological removal of organic sulfur from coal

Technical Report · Tue Jan 01 04:00:00 EST 1991

OSTI ID:5304238

Raphaelian, L A ^[1]

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1. Institute of Gas Technology, Chicago, IL (United States)

The objective of this work is to investigate techniques for chemically converting the sulfur containing organic compounds in coal to compounds that can be treated microbiologically to remove the organically bound sulfur. The goal is to achieve an economically feasible mild chemical oxidation of the organic sulfur in a representative Illinois Basin coal by converting the sulfur to sulfoxides and sulfones; the carbon sulfur bond in the sulfoxides and sulfones would then be broken microbiologically and the sulfur removed from the coal as a sulfate. In initial studies, it was found that the combination treatments of sodium periodate/microbial and hydrogen peroxide/microbial resulted in reductions of total sulfur or organic sulfur of up to 20%. 4 tabs.

• Research Organization: Illinois Dept. of Energy and Natural Resources, Springfield, IL (United States)
• Sponsoring Organization: DOE; USDOE, Washington, DC (United States)
• DOE Contract Number: FG22-90PC90176
• OSTI ID: 5304238
• Report Number(s): DOE/PC/90176-T38; ON: DE91018302
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
010402* -- Coal
Lignite
& Peat-- Purification & Upgrading
550700 -- Microbiology
59 BASIC BIOLOGICAL SCIENCES
ALKALI METAL COMPOUNDS
BIODEGRADATION
BITUMINOUS COAL
BLACK COAL
CARBONACEOUS MATERIALS
CHEMICAL REACTIONS
COAL
DECOMPOSITION
DESULFURIZATION
DOCUMENT TYPES
ENERGY SOURCES
FOSSIL FUELS
FUELS
HALOGEN COMPOUNDS
HYDROGEN COMPOUNDS
HYDROGEN PEROXIDE
IODINE COMPOUNDS
MATERIALS
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXIDATION
OXYGEN COMPOUNDS
PERIODATES
PEROXIDES
PROGRESS REPORT
SODIUM COMPOUNDS
SULFONES
SULFOXIDES