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UV and IR laser ablation for inductively coupled plasma mass spectrometry

Conference · · AIP Conference Proceedings (American Institute of Physics); (United States)
OSTI ID:5286039
; ;  [1]
  1. Pacific Northwest Laboratory, P.O. Box 999, Richland, Washington 99352 (United States)
Laser ablation particle plume compositions are characterized using inductively coupled plasma mass spectrometry (ICP/MS). This study evaluates the mass response characteristics peculiar to ICP/MS detection as a function of laser fluence and frequency. Evaluation of the ICP/MS mass response allows deductions to be made concerning how representative the laser ablation produced particle plume composition is relative to the targeted sample. Using a black glass standard, elemental fractionation was observed, primarily for alkalis and other volatile elements. The extent of elemental fractionation between the target sample and the sampled plume varied significantly as a function of laser fluences and IR and UV laser frequency.
DOE Contract Number:
AC06-76RL01830
OSTI ID:
5286039
Report Number(s):
CONF-9304144--
Conference Information:
Journal Name: AIP Conference Proceedings (American Institute of Physics); (United States) Journal Volume: 288:1
Country of Publication:
United States
Language:
English