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Microwave vitrification of Rocky Flats hydroxide precipitation sludge, Building 774. Progress report

Technical Report ·
OSTI ID:52755

This report describes the first set of experiments performed on transuranic (TRU) precipitation sludge produced in Building 774, to determine the operating parameters for the microwave vitrification process. Toxicity Characteristic Leach Procedure (TCLP) results of the raw sludge showed concentrations of lead, silver and cadmium which were in excess of land disposal restrictions (LDR). Crushed, borosilicate glass was used as a frit source to produce a highly desirable, vitrified, product that required less energy to produce. TCLP testing, of microwaved samples, showed favorable results for 40 and 50% waste loading. The results of this study are encouraging and support the development of microwave vitrification technology for the treatment of various mixed waste streams at Rocky Flats Environmental Technology Site. However, additional experiments are required to fully define the operating parameters for a production-scale system.

Research Organization:
EG and G Rocky Flats, Inc., Golden, CO (United States). Rocky Flats Plant
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC34-90RF62349
OSTI ID:
52755
Report Number(s):
RFP--4903; CONF-950216--128; ON: DE95010358
Country of Publication:
United States
Language:
English

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