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Heavy ion induced damage and disorder in intermetallic compounds with the B2 structure. [NiAl; NiTi; FeAl]

Conference ·
OSTI ID:5274191

Although the B2-type intermetallic compounds, NiAl, FeAl, NiTi and FeTi all maintained a high degree of order during irradiation, metastable phase formation was observed. Dislocation loops and network developed in NiAl and FeAl during irradiation and a nickel rich, fcc phase, most likely disordered Ni/sub 3/Al, formed in NiAl after high doses. The build-up of constitutional vacancies (excess vacancies on Ni sites) and subsequent elemental partitioning of Ni and Al can explain the formation of a nickel rich phase in NiAl. No metastable phases formed in FeAl. Dislocation loop structures did not develop in NiTi or FeTi, rather a transformation to an amorphous phase occurred at relatively low doses. The amorphous transformation results when the free energy of the crystal lattice containing a high defect concentration exceeds the free energy of the amorphous configuration.

Research Organization:
Pacific Northwest Labs., Richland, WA (USA)
DOE Contract Number:
AC06-76RL01830
OSTI ID:
5274191
Report Number(s):
PNL-SA-12388; CONF-8411198-1; ON: DE850068815
Country of Publication:
United States
Language:
English

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