Self-assembled monolayers on mosoporous supports (SAMMS) for RCRA metal removal
- Pacific Northwest National Lab., Richland, WA (United States)
The Mixed Waste Focus Area has declared mercury removal and stabilization as the first and fourth priorities among 30 prioritized deficiencies. Resource Conservation and Recovery Act (RCRA) metal and mercury removal has also been identified as a high priority at DOE sites such as Albuquerque, Idaho Falls, Oak Ridge, Hanford, Rocky Flats, and Savannah River. Under this task, a proprietary new technology, Self-Assembled Monolayers on Mesoporous Supports (SAMMS), for RCRA metal ion removal from aqueous wastewater and mercury removal from organic wastes such as vacuum pump oils is being developed at Pacific Northwest National Laboratory (PNNL). The six key features of the SAMMS technology are (1) large surface area (>900 m{sup 2}/g) of the mesoporous oxides (SiO{sub 2}, ZrO{sub 2}, TiO{sub 2}) ensures high capacity for metal loading (more than 1 g Hg/g SAMMS); (2) molecular recognition of the interfacial functional groups ensures the high affinity and selectivity for heavy metals without interference from other abundant cations (such as calcium and iron) in wastewater; (3) suitability for removal of mercury from both aqueous wastes and organic wastes; (4) the Hg-laden SAMMS not only pass TCLP tests, but also have good long-term durability as a waste form because the covalent binding between mercury and SAMMS has good resistance to ion exchange, oxidation, and hydrolysis; (5) the uniform and small pore size (2 to 40 nm) of the mesoporous silica prevents bacteria (>2000 nm) from solubilizing the bound mercury; and (6) SAMMS can also be used for RCRA metal removal from gaseous mercury waste, sludge, sediment, and soil.
- Research Organization:
- Science, Inc., Anaheim, CA (United States)
- OSTI ID:
- 527214
- Report Number(s):
- PNNL-SA-28461-Rev.1; CONF-970148-Rev.1; ON: DE97052111; TRN: 97:015057
- Resource Relation:
- Conference: Efficient Separations and Processing (ESP) Crosscutting Program FY 1997 technical exchange meeting, Gaithersburg, MD (United States), 28-30 Jan 1997; Other Information: PBD: [1997]; Related Information: Is Part Of Proceedings of the efficient separations and processing crosscutting program 1997 technical exchange meeting; Gephart, J.M. [ed.]; PB: 211 p.
- Country of Publication:
- United States
- Language:
- English
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