Oxygen in activator centers of zinc sulfide

Journal Article · Thu May 01 04:00:00 EDT 1986 · J. Appl. Spectrosc. (Engl. Transl.); (United States)

OSTI ID:5266719

Golobeva, N P; Fok, M V

The authors observed the sensitized luminescence of Tm and Dy without addition of Cu and Ag in samples which had been obtained by the sulfonation of zinc sulfide in hydrogen sulfide; the zinc sulfide has a copper concentration below 5.10/sup -6/ mass %. In this case the excitation can be transmitted from the ZnS lattice to the rare-earth activators mainly through defects including oxygen. The following conclusions were made. In the case of activated ZnS, oxygen is present in formations accounting for the excitation and luminescence of a number of luminophors. When an activator is introduced in the region of ZnS layer faults, where also the oxygen must be located, the positioning of the faults in close vicinity is facilitated even when the oxygen concentration of the ZnS is low. All this must be considered when models of luminescence centers of zinc sulfide are developed.

• OSTI ID: 5266719
• Journal Information: J. Appl. Spectrosc. (Engl. Transl.); (United States), Journal Name: J. Appl. Spectrosc. (Engl. Transl.); (United States) Vol. 43:5; ISSN JASYA
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360202 -- Ceramics
Cermets
& Refractories-- Structure & Phase Studies
360204* -- Ceramics
Cermets
& Refractories-- Physical Properties
ABSORPTION SPECTRA
CHALCOGENIDES
CHARGE TRANSPORT
CRYSTAL DOPING
CRYSTAL MODELS
DYSPROSIUM
DYSPROSIUM COMPOUNDS
ELEMENTS
EMISSION SPECTRA
INORGANIC PHOSPHORS
LATTICE PARAMETERS
LUMINESCENCE
MATHEMATICAL MODELS
METALS
NONMETALS
OXIDES
OXYGEN
OXYGEN COMPOUNDS
PHOSPHORS
RARE EARTH COMPOUNDS
RARE EARTHS
RECOMBINATION
SPECTRA
SULFIDES
SULFUR COMPOUNDS
THULIUM
THULIUM COMPOUNDS
ZINC COMPOUNDS
ZINC OXIDES
ZINC SULFIDES