Solar selective black cobalt: preparation, structure, and thermal stability

Journal Article · Fri Aug 01 00:00:00 EDT 1980 · J. Appl. Phys.; (United States)

DOI:https://doi.org/10.1063/1.328276· OSTI ID:5265169

Smith, G B; Ignatiev, A; Zajac, G

In the quest for an electroplated selective black coating stable to 500 /sup 0/C in air, black cobalts have been prepared by three techniques to yield (a) plated cobalt sulphides, (b) plated cobalt oxide-hydroxide, and (c) cobalt oxide prepared by thermal oxidation of electropolated cobalt metal. The optical properties of the various coatings are analyzed before and after exposure to air for extended periods of time at temperatures in the 300 /sup 0/--500 /sup 0/C range. The sulfide black cobalt is not acceptable as a high-temperature selective absorber due to severe thermal degradation. The plated oxide is a good selective absorber to about 400 /sup 0/C, and the thermally oxidized black to a slightly higher temperature, but degrades at 500 /sup 0/C. Structure studies via scanning electron microscopy (SEM), Auger electron spectroscopy (AES), and x-ray photoemission spectroscopy (XPS) are reported which yield a full account of the coating chemistry before and after heating. The studies reveal that the high solar absorptance of the acceptable black cobalt coatings is due to a continuation of a porous outer layer grading into nondense oxides of cobalt; either CoO or Co/sub 3/O/sub 4/, depending on the film. Absorption is intrinsic but not due to metal particles as in black chrome. A limited amount of optical degradation occurs upon heating the oxide black cobalt in air due to oxidation of hydroxide. However, the major degradation problem is shown to be substrate oxidation in contrast to black chrome where film oxidation is the principal problem.

• Research Organization: Department of Physics, University of Houston, Houston, Texas, 77004
• OSTI ID: 5265169
• Journal Information: J. Appl. Phys.; (United States), Journal Name: J. Appl. Phys.; (United States) Vol. 51:8; ISSN JAPIA
• Country of Publication: United States
• Language: English

Related Subjects

14 SOLAR ENERGY
140501* -- Solar Energy Conversion-- Photovoltaic Conversion
ABSORPTION
AUGER ELECTRON SPECTROSCOPY
BLACK COATINGS
CHALCOGENIDES
COATINGS
COBALT COMPOUNDS
COBALT HYDROXIDES
COBALT OXIDES
COBALT SULFIDES
DATA
ELECTRON MICROSCOPES
ELECTRON SCANNING
ELECTRON SPECTROSCOPY
FABRICATION
HIGH TEMPERATURE
HYDROGEN COMPOUNDS
HYDROXIDES
INFORMATION
MECHANICAL PROPERTIES
MICROSCOPES
OPTICAL PROPERTIES
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
RADIATIONS
SOLAR RADIATION
SPECTROSCOPY
STABILITY
SULFIDES
SULFUR COMPOUNDS
SURFACES
THERMAL DEGRADATION
THERMODYNAMIC PROPERTIES
TRANSITION ELEMENT COMPOUNDS