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Exploratory research on silicon nitride composites. Final report

Technical Report ·
OSTI ID:5264720
Possibilities of making silicon nitride composites, reinforced with various ceramic fibers, by reaction bonding of particulate silicon matrices were explored with the objective of increasing material toughness. Two fabrication methods were developed using low volume fractions of fibers: lamination of CVD filaments between thin foils of polymer-bonded silicon; and casting of composites containing continuous or chopped fine fibers or filaments with aqueous or non-aqueous silicon slips. Further work is required to increase matrix density, optimize fiber/matrix bonding and increase fiber volume fraction. Both high modulus chemical vapor deposited silicon carbide filaments and low modulus boron nitride fine fibers were found to be compatible with reaction bonding processing. Poor matrix bonding resulted with fine silicon carbide fibers made from a polycarbosilane polymer precursor, because of a surface degradation reaction.
Research Organization:
Washington Univ., Seattle (USA). Dept. of Mining and Metallurgical and Ceramic Engineering
DOE Contract Number:
FG01-78ET13389
OSTI ID:
5264720
Report Number(s):
DOE/ET/13389-T1; ON: DE82017286
Country of Publication:
United States
Language:
English