Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Absolute rates of hydrogen abstraction by tert-butoxy radicals

Journal Article · · J. Am. Chem. Soc.; (United States)
DOI:https://doi.org/10.1021/ja00469a058· OSTI ID:5252094
;
The reaction of tert-butoxy radicals with diphenylmethanol and with cumene was examined using nanosecond laser flash photolysis techniques in order to determine the absolute values of the rates of reaction of the radicals. The absolute rate measured for both substrates compare favorably with the values for the benzophenone triplet. (JSR)
Research Organization:
Univ. of Notre Dame, IN
OSTI ID:
5252094
Journal Information:
J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 100:1; ISSN JACSA
Country of Publication:
United States
Language:
English

Similar Records

Hydrogen abstraction by tert-butoxy radicals. A laser photolysis and electron spin resonance study
Journal Article · Wed Jul 05 00:00:00 EDT 1978 · J. Am. Chem. Soc.; (United States) · OSTI ID:6740847
Quenching of triplet benzophenone by 2,4,6-tri-tert-butylphenol and formation of its phenoxy radical
Journal Article · Thu May 21 00:00:00 EDT 1987 · J. Phys. Chem.; (United States) · OSTI ID:6508625
Laser-induced fluorescence excitation spectra of tert-butoxy and 2-butoxy radicals
Journal Article · Thu Oct 14 00:00:00 EDT 1999 · Journal of Physical Chemistry A: Molecules, Spectroscopy, Kinetics, Environment, amp General Theory · OSTI ID:20001148

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
ALCOHOLS
ALKOXY RADICALS
AROMATICS
BUTOXY RADICALS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CUMENE
DECOMPOSITION
HYDROCARBONS
HYDROXY COMPOUNDS
KINETICS
ORGANIC COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
RADICALS
REACTION KINETICS