Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

The effects of irradiation on the thermal conductivity of sintered Li sub 2 O and. gamma. -LiAlO sub 2

Thesis/Dissertation ·
OSTI ID:5246022
Li{sub 2}O and LiAlO{sub 2} are two candidates for solid breeder materials in the United States' Fusion Power Program. Critical to fusion reactor breeder design efforts are thermophysical data - the bulk of which have only recently become available for unirradiated lithium ceramics. This investigation expands the current limited data base by presenting thermal-conducting data between 373-1173 K for both materials following fast-neutron irradiation. Samples were irradiated at 773-1173 K to lithium burnups {le} 11.5 {times} 10{sup 20} captures/cm{sup 3}. Comparisons are made between these data and those from unirradiated archive samples of the same materials. Significant reductions in thermal conductivity of both materials were observed at all irradiation times and temperatures. The reduction is attributed to crystallographic lattice damage resulting from the interaction of lattice atoms with high-energy neutrons. At lithium burnups greater than about 7 {times} 10{sup 20} capts/cm{sup 3}, measured thermal conductivity values (at 500 K) stabilized at approximately 70% of unirradiated values for both Li{sub 2}O and LiAlO{sub 2}. The most significant reductions occurred at low measurement temperatures.
Research Organization:
Washington Univ., Seattle, WA (USA)
OSTI ID:
5246022
Country of Publication:
United States
Language:
English