Observation of phase selection from dendrite growth in undercooled Fe-Ni-Cr melts

Journal Article · Tue Jul 01 04:00:00 EDT 1997 · Acta Materialia

DOI:https://doi.org/10.1016/S1359-6454(96)00376-X· OSTI ID:524539

Moir, S A; Herlach, D M ^[1]

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1. Deutsche Forschungsanstalt fuer Luft- und Raumfahrt, Koeln (Germany). Inst. fuer Raumsimulation

The electromagnetic levitation method was applied to conduct in-situ observations of phase selection processes in undercooled metal drops. By means of a high-speed photosensing diode with a sampling rate of 1 MHz focused onto two adjacent areas of a droplet surface, the passing of a solidification wave front can be recorded and thereby the growth velocities calculated. The alloys studied were Fe{sub 69}Cr{sub 51{minus}x}Ni{sub x} where x was varied between 12 and 24, and equilibrium are f.c.c. structure (austenitic phase) but when undercooled sufficiently nucleate the b.c.c. (ferritic) phase. The dendrite growth velocities showed a clear break at the transition from the b.c.c. to the f.c.c. profile of the respective growth velocity-undercooling curves. A two-fold explanation is found for the clear break; firstly there is a contrast between the lower undercooling f.c.c. phase which travels relatively faster for the same undercooling. Secondly, the liquidus temperatures for the two phases are offset so that for the metastable b.c.c. phase, the b.c.c.-f.c.c. liquidi temperature difference increases significantly with increasing nickel content. The result is two easily identifiable curves for the separate phase growth modes; f.c.c. at lower undercoolings and metastable b.c.c. at higher undercoolings. It was also found that these alloys show a trend towards increasing undercooling necessary to nucleate the metastable b.c.c. phase with increasing nickel content. A number of nucleation theories have been applied to explain this behavior, namely Classical Nucleation Theory (CNT) and Diffuse Interface Theory (DIT). Two recent forms for the latter DIT theory have been proposed and both were applied to this system. The results show that by optimizing the nucleus composition all predictions were seen to lie much closer to the experimental results. The DIT theory by Granasy was found to give the closest agreement to experiment after optimization of the nucleus composition.

• Sponsoring Organization: Commission of the European Communities, Brussels (Belgium)
• OSTI ID: 524539
• Journal Information: Acta Materialia, Journal Name: Acta Materialia Journal Issue: 7 Vol. 45; ISSN 1359-6454; ISSN ACMAFD
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
CHROMIUM ALLOYS
DENDRITES
EXPERIMENTAL DATA
IRON ALLOYS
LEVITATION
LIQUID METALS
NICKEL ALLOYS
NUCLEATION
PHASE STUDIES
SOLIDIFICATION