Mechanism of plagioclase dissolution in acid solution at 25[degrees]C
- Univ. of Wyoming, Laramie, WY (United States)
The dissolution kinetics of three plagioclase feldspars (An[sub 13], An[sub 46], and An[sub 76]) were studied in flow-through reactors over the pH range 3-7. In accordance with the surface complexation model, dissolution rate was described by the equation Rate = [chi][sub a]A exp(E[sub a]/kT) (C[sup 5][sub H])[sup n], where (C[sup 5][sub H]) is the concentration of protonated surface sites, [chi][sub a] is the mole fraction of these that are activated, A is the Arrhenius pre-exponential factor, and E[sub a] is the activation energy for the reaction. The reaction order with respect to surface charge (n) at pH < 5 is a function of mineral composition, and increases with increasing anorthite content. Orders of 0.46, 1.2, and 2.0 are obtained for oligoclase, andesine, and bytownite, respectively. This indicates that the reaction intermediate is more highly protonated in feldspars of higher aluminum content. The nonintegral reaction orders obtained demonstrate the importance of several surface species in the dissolution reaction. Reaction rates increase with increasing anorthite content. In acid solution this reflects the linear dependence of E[sub a] on the number of Al-O-Si bonds involved in the rate-determining step. Under conditions of low surface protonation (in near-neutral solutions), dissolution is independent of surface charge. As reaction occurs at neutral alumina sites, the rate is approximately proportional to the anorthite (Al) content of the feldspar.
- OSTI ID:
- 5223355
- Journal Information:
- Geochimica et Cosmochimica Acta; (United States), Journal Name: Geochimica et Cosmochimica Acta; (United States) Vol. 58:2; ISSN GCACAK; ISSN 0016-7037
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
400201* -- Chemical & Physicochemical Properties
54 ENVIRONMENTAL SCIENCES
540210 -- Environment
Terrestrial-- Basic Studies-- (1990-)
ACID RAIN
ANORTHOSITES
ATMOSPHERIC PRECIPITATIONS
CHEMICAL REACTION KINETICS
DISSOLUTION
FELDSPARS
GABBROS
IGNEOUS ROCKS
KINETICS
MINERALS
PH VALUE
PLUTONIC ROCKS
RAIN
REACTION KINETICS
ROCKS
SILICATE MINERALS